منابع مشابه
3,5-Dichloro-6-methylpyridin-2-amine
In the title compound, C(6)H(6)Cl(2)N(2), intra-molecular N-H⋯Cl and C-H⋯Cl contacts generate five-membered rings, producing S(5) ring motifs. Pairs of inter-molecular N-H⋯N hydrogen bonds link neighbouring mol-ecules into dimers with R(2) (2)(8) ring motifs. In the crystal structure, these dimers are connected by N-H⋯Cl inter-actions and are packed into columns.
متن کاملChlorido(4-methylpyridin-2-amine-κN 1)(2-{[(4-methylpyridin-2-yl)imino-κN]methyl}phenolato-κO)copper(II)
In the title complex, [Cu(C13H11N2O)Cl(C6H8N2)], the Cu(II) atom adopts a distorted tetra-hedral geometry being coordinated by the phenolic O atom and the azomethine N atom of the Schiff base ligand N-salicyl-idene 2-amino-pyridine, and by the 2-amino-pyridine N atom and a Cl atom. The pyridyl N atom of the Schiff base and the imino N atom of the 4-methyl-pyridine-2-yl-imino ligand are not invo...
متن کامل6-Methylpyridin-2-amine
In the title mol-ecule, C6H8N2, the endocyclic angles are in the range 118.43 (9)-122.65 (10)°. The mol-ecular skeleton is planar (r.m.s. deviation = 0.007 Å). One of the two amino H atoms is involved in an N-H⋯N hydrogen bond, forming an inversion dimer, while the other amino H atom participates in N-H⋯π inter-actions between the dimers, forming layers parallel to (100).
متن کاملStructure and dioxygen-reactivity of copper(I) complexes supported by bis(6-methylpyridin-2-ylmethyl)amine tridentate ligands.
The structure and dioxygen-reactivity of copper(I) complexes R supported by N,N-bis(6-methylpyridin-2-ylmethyl)amine tridentate ligands L2R[R (N-alkyl substituent)=-CH2Ph (Bn), -CH2CH2Ph (Phe) and -CH2CHPh2(PhePh)] have been examined and compared with those of copper(I) complex (Phe) of N,N-bis[2-(pyridin-2-yl)ethyl]amine tridentate ligand L1(Phe) and copper(I) complex (Phe) of N,N-bis(pyridin-...
متن کامل2,4-Dichloro-6-({2-[(3,5-dichloro-2-hydroxybenzylidene)amino]ethyl}iminomethyl)phenol
The title mol-ecule, C(16)H(12)Cl(4)N(2)O(2), lies about an inversion center. The symmetry-unique part of the mol-ecule contains an intra-molecular O-H⋯N hydrogen bond. In the crystal, mol-ecules are arranged in corrugated layers parallel to (-101). Weak π-π stacking inter-actions, with a centroid-centroid diatance of 3.7923 (13) Å, are present.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808041366